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Effect of surface wettability on microfluidic EDGE emulsification.

Abid Aslam Maan1, Sami Sahin, Liyakat Hamid Mujawar

  • 1Wageningen University, Food Process Engineering Group, Wageningen, The Netherlands. abid.maan@yahoo.com

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Wettability significantly impacts microfluidic emulsification. Optimal droplet size and uniformity were achieved at high contact angles, but stability improved at slightly lower angles, revealing a trade-off for controlled emulsion generation.

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Area of Science:

  • Microfluidics
  • Colloid and Surface Science
  • Emulsion Technology

Background:

  • Microfluidic emulsification offers precise control over droplet generation.
  • Wettability is a critical parameter influencing interfacial phenomena in microfluidic devices.
  • Understanding wettability effects is crucial for optimizing emulsion characteristics.

Purpose of the Study:

  • To investigate the influence of dispersed phase contact angles on microfluidic EDGE emulsification.
  • To determine the relationship between wettability and emulsion properties like droplet size, uniformity, and stability.
  • To identify optimal wettability conditions for producing monodispersed emulsions with enhanced stability.

Main Methods:

  • Microfluidic EDGE emulsification experiments were conducted.
  • Contact angles were varied between 90° and 160°.
  • Droplet size, coefficient of variation, pressure stability, and droplet generation frequency were analyzed.

Main Results:

  • The highest contact angle (160°) yielded monodispersed emulsions (5.0 μm, CV <10%) but with low pressure stability.
  • Enhanced pressure stability and increased droplet generation frequencies (up to 2.0x for Tween20, 3.5x for Tween60) were observed at contact angles <150°.
  • High polydispersity occurred at contact angles <100° due to wetting by the dispersed phase.

Conclusions:

  • Wettability plays a crucial role in microfluidic emulsification, affecting both droplet characteristics and process stability.
  • A contact angle below 150° is necessary for achieving stable and efficient microfluidic emulsification.
  • Careful control of wettability is essential for tailoring emulsion properties in microfluidic systems.