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Updated: May 11, 2026

Functionalization of Single-walled Carbon Nanotubes with Thermo-reversible Block Copolymers and Characterization by Small-angle Neutron Scattering
Published on: June 1, 2016
Tungsten disulphide sheathed carbon nanotubes.
R L Whitby1, W K Hsu, C B Boothroyd
1School of Chemistry, Physics and Environmental Science, University of Sussex, Brighton, UK.
Researchers created insulated nanotube wires using tungsten disulfide and carbon nanotubes. The tungsten disulfide coating effectively protects the nanotubes from oxidation at high temperatures.
Area of Science:
- Materials Science
- Nanotechnology
- Chemistry
Background:
- Carbon nanotubes (CNTs) offer excellent electrical and mechanical properties.
- Insulating CNT-based wires are desirable for advanced electronics.
- Protecting CNTs from oxidation is crucial for device longevity.
Purpose of the Study:
- To develop a novel insulated nanotube wire.
- To investigate the protective properties of tungsten disulfide (WS2) coatings on CNTs.
Main Methods:
- Synthesized WS2-coated multiwalled carbon nanotubes (MWCNTs) via sulphidization of tungsten oxide.
- Coated MWCNTs with tungsten oxide and then heated at 900 °C in a sulfur-containing atmosphere.
- Characterized the resulting binary phase material using High-Resolution Transmission Electron Microscopy (HRTEM).
- Evaluated the antioxidant properties using Thermogravimetric Analysis (TGA).
Main Results:
- Successfully formed insulated nanotube wires composed of a binary phase of layered WS2 and CNTs.
- HRTEM confirmed the layered structure of WS2 on CNTs.
- TGA demonstrated that the WS2 coating acts as an effective antioxidant, protecting the CNTs.
Conclusions:
- The developed WS2/CNT composite material provides effective insulation and oxidation protection.
- This method offers a viable route for fabricating robust CNT-based wires for high-temperature applications.
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