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Updated: May 11, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
Published on: June 24, 2022
Effect of oxide supports in stabilizing desirable Pt-Ni bimetallic structures for hydrogenation and reforming
Tiefeng Wang1, Giannis Mpourmpakis, William W Lonergan
1Beijing Key Laboratory of Green Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China. wangtf@tsinghua.edu.cn
Abstract:
Previous surface science studies have shown that bimetallic surfaces often show unique activity for reactions involving the consumption and production of hydrogen, such as hydrogenation and reforming reactions, respectively. These two types of reactions require different bimetallic configurations. For example, for the Pt-Ni bimetallic system, the desirable structure is Pt-terminated for hydrogenation while Ni-terminated for reforming. In the current study, 1,3-butadiene hydrogenation and ethanol reforming were used as probe reactions to investigate the effect of oxide supports (γ-Al2O3 and TiO2) on the structural and catalytic properties of Pt-Ni catalysts. The supported catalysts were characterized by transmission electron microscopy (TEM) and extended X-ray absorption fine structure (EXAFS). The reactions were carried out in a batch reactor equipped with a Fourier transform infrared (FTIR) spectrometer. For ethanol reforming, Pt-Ni/TiO2 showed higher activity than Pt-Ni/γ-Al2O3, and the Pt-Ni bimetallic catalyst outperformed the monometallic catalysts on TiO2 but not on γ-Al2O3. In contrast, for 1,3-butadiene hydrogenation, Pt-Ni/TiO2 showed much lower activity than Pt-Ni/γ-Al2O3. Density functional theory (DFT) calculations of Pt-Ni nanoparticles on γ-Al2O3 and TiO2 were performed to provide possible explanations for the different modification effects of the two oxide supports.
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