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Related Experiment Video

Updated: May 11, 2026

Origami Inspired Self-assembly of Patterned and Reconfigurable Particles
12:33

Origami Inspired Self-assembly of Patterned and Reconfigurable Particles

Published on: February 4, 2013

Competition of shape and interaction patchiness for self-assembling nanoplates.

Xingchen Ye1, Jun Chen, Michael Engel

  • 1Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.

Nature Chemistry
|May 23, 2013
PubMed
Summary

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Lanthanide fluoride nanoplates self-assemble into ordered tilings, driven by shape and atomic edge interactions. This reveals unconventional assembly pathways beyond simple packing density for advanced nanomaterials.

Area of Science:

  • Materials Science
  • Nanotechnology
  • Crystallography

Background:

  • Nanocrystal synthesis enables ordered superlattices.
  • Focus on spherical and polyhedral particles, with shape effects underexplored.
  • Planar lanthanide fluoride nanocrystals offer new possibilities.

Purpose of the Study:

  • Investigate self-assembly of faceted lanthanide fluoride nanoplates.
  • Understand the role of shape and edge interactions in ordering.
  • Explore formation of unconventional superlattices.

Main Methods:

  • Experimental synthesis and self-assembly at liquid-air interface.
  • Multiscale computational investigation using Monte Carlo simulations.
  • Density Functional Theory (DFT) for atomic structure analysis.

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Grafting Multiwalled Carbon Nanotubes with Polystyrene to Enable Self-Assembly and Anisotropic Patchiness
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Grafting Multiwalled Carbon Nanotubes with Polystyrene to Enable Self-Assembly and Anisotropic Patchiness

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A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
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A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

Published on: May 9, 2014

Related Experiment Videos

Last Updated: May 11, 2026

Origami Inspired Self-assembly of Patterned and Reconfigurable Particles
12:33

Origami Inspired Self-assembly of Patterned and Reconfigurable Particles

Published on: February 4, 2013

Grafting Multiwalled Carbon Nanotubes with Polystyrene to Enable Self-Assembly and Anisotropic Patchiness
11:09

Grafting Multiwalled Carbon Nanotubes with Polystyrene to Enable Self-Assembly and Anisotropic Patchiness

Published on: April 1, 2018

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
08:09

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

Published on: May 9, 2014

Main Results:

  • Nanoplates form long-range ordered tilings.
  • Assembly is influenced by packing density, but edge interactions are crucial.
  • Atomic structure of edges dictates specific interactions.

Conclusions:

  • Shape-induced entropy and edge-specific energetics drive assembly.
  • Unconventional ordered structures are formed.
  • Exploiting shape and atomic details enables novel nanomaterial assembly.