Related Experiment Video
Updated: May 11, 2026

High-Temperature and High-Pressure In situ Magic Angle Spinning Nuclear Magnetic Resonance Spectroscopy
Published on: October 9, 2020
[Vibrational and rotational spectrum of carbon monoxide at high temperature]
Xin-Hua Qi1, Tie Su, Fu-Rong Yang
1State Key Laboratory of Aerodynamics, China Aerodynamics Research and Development Center, Mianyang 621000, China. qxh_78@sina.com
Abstract:
The total partition function was calculated for carbon monoxide with approximation. Using the dipole moment function and the wave function with Morse approximation, we computed the matrix elements of vibrational-rotational transition and absorption coefficient at normal and high temperature. The computed results agreed with the HITRAN database and literature, which shows that the calculation of total partition function and matrix elements of vibrational-rotational transition is reliable. Furthermore, the absorption coefficient and radiant spectrum are also presented at higher temperature of 4 000 and 6 000 K.
More Related Videos
09:40Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown
Published on: February 14, 2014
11:38In situ FTIR Spectroscopy as a Tool for Investigation of Gas/Solid Interaction: Water-Enhanced CO2 Adsorption in UiO-66 Metal-Organic Framework
Published on: February 1, 2020
Related Concept Videos
IR Spectroscopy: Molecular Vibration Overview
Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...
IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration
According to Hooke's law, the vibrational frequency is directly proportional to the...
Atomic Spectroscopy: Effects of Temperature
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature from...
UV–Vis Spectroscopy: Molecular Electronic Transitions
Molecular Spectroscopy: Absorption and Emission
IR and UV–Vis Spectroscopy of Aldehydes and Ketones