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Updated: May 11, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Communication: Pressure fluctuations in isotropic solids and fluids
J P Wittmer1, H Xu, P Polińska
1Institut Charles Sadron, Université de Strasbourg and CNRS, 23 rue du Loess, 67034 Strasbourg Cedex, France. joachim.wittmer@ics-cnrs.unistra.fr
Abstract:
Comparing isotropic solids and fluids at either imposed volume or pressure, we investigate various correlations of the instantaneous pressure and its ideal and excess contributions. Focusing on the compression modulus K, it is emphasized that the stress fluctuation representation of the elastic moduli may be obtained directly (without a microscopic displacement field) by comparing the stress fluctuations in conjugated ensembles. This is made manifest by computing the Rowlinson stress fluctuation expression K(row) of the compression modulus for NPT-ensembles. It is shown theoretically and numerically that K(row∣P) = P(id)(2 - P(id)∕K) with P(id) being the ideal pressure contribution.
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