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Updated: May 11, 2026

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Numerical study of a slip-link model for polymer melts and nanocomposites
Diego Del Biondo1, Elian M Masnada, Samy Merabia
1Univ. Lyon I, Laboratoire de Physique de la Matière Condensée et des Nanostructures, CNRS, UMR 5586, 43 Bvd. du 11 Nov. 1918, 69622 Villeurbanne Cedex, France.
Abstract:
We present a numerical study of the slip link model introduced by Likhtman for describing the dynamics of dense polymer melts. After reviewing the technical aspects associated with the implementation of the model, we extend previous work in several directions. The dependence of the relaxation modulus with the slip link density and the slip link stiffness is reported. Then the nonlinear rheological properties of the model, for a particular set of parameters, are explored. Finally, we introduce excluded volume interactions in a mean field such as manner in order to describe inhomogeneous systems, and we apply this description to a simple nanocomposite model. With this extension, the slip link model appears as a simple and generic model of a polymer melt, that can be used as an alternative to molecular dynamics for coarse grained simulations of complex polymeric systems.
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