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Updated: May 10, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
3-[(1-Bromo-naphthalen-2-yl)meth-oxy]-5,5-di-methyl-cyclo-hex-2-enone
Liang-Liang Fang1, Nan Liu, Xin-Ying Zhang
1School of Chemistry and Chemical Engineering, Henan Normal University, Henan 453007, People's Republic of China.
Abstract:
In the title compound, C19H19BrO2, the cyclo-hexenone ring adopts an envelope conformation with the C atom bearing the methyl substituents as the flap. In the crystal, weak π-π stacking is observed between parallel aromatic rings of adjacent mol-ecules, the centroid-centroid distance being 3.694 (6) Å. The entire bromonaphthylmethyl unit is disordered over two orientations, with a site-occupancy ratio of 0.5214 (19):0.4786 (19).
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