Intense ultra-broadband down-conversion in co-doped oxide glass by multipolar interaction process

We report that Eu(2+) can be an efficient sensitizer for Yb(3+) and a broadband absorber for blue solar spectra in the host of oxide glass. The greenish 4f → 5d transition of Eu(2+) and the characteristic near-infrared emission of Yb(3+) were observed, with the blue-light of xenon lamp excitation. The 5d energy can be adjusted by the host and the energy transfer efficiency can be enhanced. The quantum efficiency is up to 163.8%. Given the broad excitation band, high absorption coefficient and excellent mechanical, thermal and chemical stability, this system can be useful as down-conversion layer for solar cells.