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Updated: May 10, 2026

The Effect of Interfacial Chemical Bonding in TiO2-SiO2 Composites on Their Photocatalytic NOx Abatement Performance
Published on: July 4, 2017
Band gap narrowing of titanium dioxide (TiO2) nanocrystals by electrochemically active biofilms and their visible
Shafeer Kalathil1, Mohammad Mansoob Khan, Sajid Ali Ansari
1School of Chemical Engineering, Yeungnam University, Gyeongsan-si, Gyeongbuk 712-749, South Korea.
Abstract:
We report a simple biogenic-route to narrow the band gap of TiO2 nanocrystals for visible light application by offering a greener method. When an electrochemically active biofilm (EAB) was challenged with a solution of Degussa-TiO2 using sodium acetate as the electron donor, greyish blue-colored TiO2 nanocrystals were obtained. A band gap study showed that the band gap of the modified TiO2 nanocrystals was significantly reduced (E(g) = 2.85 eV) compared to the unmodified white Degussa TiO2 (E(g) = 3.10 eV).

