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Synthesis of Persistent Luminescent Nanoparticles for Rewritable Displays and Illumination Applications
Published on: September 13, 2024
Syntheses, structures, tunable emission and white light emitting Eu3+ and Tb3+ doped lanthanide metal-organic
Ming-Li Ma1, Can Ji, Shuang-Quan Zang
1The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, PR China.
Abstract:
A series of novel lanthanide metal-organic frameworks, namely, {[Ln2(L)2]·(H2O)3·(Me2NH2)2}n (Ln = La (1), Ce (2), Pr (3), Nd (4), Sm (5), Eu (6), Gd (7), Tb (8), Ho (9), Er (10)), have been synthesized with hydro(solvo)thermal conditions based on a flexible multicarboxylic acid (H4L = 5-(3,5-dicarboxybenzyloxy)isophthalic acid). Single crystal X-ray diffraction reveals that all of them are isomorphous and possess a (6,6) topological net with a Schläfli symbol of {4(8)·6(7)}. Considering the blue-emission of compound 1 and the intense emission of the Eu and Tb compounds, we successfully construct isostructural Eu(3+) doped Tb compounds whose color can be tuned easily by adjusting the different concentration of the doped ions, and we also obtained white light emitting materials through the doping of Eu and Tb ions in the La compounds.
