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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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Published on: April 10, 2015

Rhodium and iridium complexes with a new scorpionate phosphane ligand

Angel L Serrano1, Miguel A Casado, José A López

  • 1Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC, Universidad de Zaragoza, Pedro Cerbuna 12, 50009 Zaragoza, Spain.

Inorganic Chemistry
|June 15, 2013
PubMed
Summary

A new hybrid scorpionate ligand, [A2BPN](-), was synthesized and coordinated to rhodium and iridium. This ligand exhibits versatile binding modes, influencing the electronic properties and reactivity of the resulting metal complexes.

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