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Synthesis, spectroscopic (FT-IR/NMR) characterization, X-ray structure and DFT studies on (E)-2-(1-phenylethylidene)

Namık Ozdemir1, Ersin Inkaya, Emin Sarıpınar

  • 1Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139 Samsun, Turkey. namiko@omu.edu.tr

Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy
|June 18, 2013
PubMed

Keywords:
AminoguanidineCrystal structureDFT calculationsIR and NMR spectroscopyMolecular electrostatic potential (MEP)Non-linear optical properties

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Enamine formation involves the addition of carbonyl compounds to a secondary amine through a series of reactions. The mechanism begins with the generation of carbinolamine, a nucleophilic attack followed by several proton transfer reactions. The hydroxyl group of the carbinolamine is converted into water to make a better leaving group that can push the reaction forward by eliminating a water molecule. In enamine formation, the last step involves the abstraction of a proton from the α carbon to...
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