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Related Concept Videos

Cationic Chain-Growth Polymerization: Mechanism00:57

Cationic Chain-Growth Polymerization: Mechanism

The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the generated carbocation,...
Anionic Chain-Growth Polymerization: Overview01:20

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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
Types of Step-Growth Polymers: Polyesters01:20

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The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
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A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
Anionic Chain-Growth Polymerization: Mechanism01:04

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The mechanism for anionic chain-growth polymerization involves initiation, propagation, and termination steps. In the initiation step, a nucleophilic anion, such as butyl lithium, initiates the polymerization process by attacking the π bond of the vinylic monomer. As a result, a carbanion, stabilized by the electron‐withdrawing group, is generated. The resulting carbanion acts as a Michael donor in the propagation step and attacks the second vinylic monomer, which acts as a Michael acceptor.
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Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta catalyst, high molecular...

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Electroactive Polymer Nanoparticles Exhibiting Photothermal Properties
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Highly enhanced energy conversion from the streaming current by polymer addition.

Trieu Nguyen1, Yanbo Xie, Lennart J de Vreede

  • 1BIOS lab on chip group, MESA+ Institution of Nanotechnology, University of Twente, Enschede, The Netherlands.

Lab on a Chip
|June 19, 2013
PubMed
Summary

Adding polyacrylic acid (PAA) to electrolyte solutions significantly boosts energy conversion efficiency from streaming current. This polymer addition enhances power output in microchannel systems, offering practical energy harvesting applications.

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Area of Science:

  • Electrochemistry
  • Materials Science
  • Energy Conversion

Background:

  • Streaming current generation is a known phenomenon in fluid dynamics.
  • Energy conversion from streaming current has potential for microscale power generation.
  • The effect of polymers on streaming current and energy conversion efficiency is not well understood.

Purpose of the Study:

  • To investigate the impact of adding polyacrylic acid (PAA) on energy conversion efficiency from streaming current.
  • To quantify the changes in streaming current, streaming potential, and input/output power.
  • To explore the potential of this method for microchannel-array energy conversion systems.

Main Methods:

  • Experimentally measured streaming current and streaming potential in KCl solutions with varying PAA concentrations.
  • Analyzed input power (flow rate × pressure) and output power.
  • Compared energy conversion efficiency with and without PAA, and with a non-ionic polymer (PEO).

Main Results:

  • Polyacrylic acid (PAA) addition drastically reduced input power while maintaining output power.
  • Streaming current increased and streaming potential decreased with PAA addition.
  • Energy conversion efficiency increased by a factor of 447 (±2%) in 0.01 mM KCl and 249 (±4%) in 1 mM KCl with PAA.

Conclusions:

  • Polyacrylic acid significantly enhances energy conversion efficiency from streaming current in electrolyte solutions.
  • The observed efficiency increase is attributed to the combined effects of increased streaming current and decreased streaming potential.
  • This finding presents a promising approach for developing efficient microchannel-array energy conversion devices.