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Peripheral arylation of subporphyrazines

Tomohiro Higashino1, M Salomé Rodríguez-Morgade, Atsuhiro Osuka

  • 1Departamento de Química Orgánica, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid, Spain.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|June 21, 2013
PubMed
Summary

Synthesized hexaarylated subporphyrazines (SubPzs) exhibit tunable electronic properties influenced by aryl substituents. Electron-donating groups cause significant spectral shifts and altered reduction potentials in these novel macrocycles.

Keywords:
arylationconjugationcross-couplingelectrochemistryporphyrins

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