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Novel expanded porphyrin sensitized solar cells using boryl oxasmaragdyrin as the sensitizer
Sandeep B Mane1, Jyun-Yu Hu, Yu-Cheng Chang
1Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan.
Chemical Communications (Cambridge, England)
|June 25, 2013
Abstract:
Oxasmaragdyrin boron complexes were prepared and applied in DSSCs. The HOMO-LUMO energy gap analyses and theoretical calculations revealed that these expanded porphyrins are ideal sensitizers for DSSCs. A device containing oxasmaragdyrin-BF2 as the sensitizer achieves an energy conversion efficiency of 5.7%.
