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Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes
12:07

Microwave-assisted Intramolecular Dehydrogenative Diels-Alder Reactions for the Synthesis of Functionalized Naphthalenes/Solvatochromic Dyes

Published on: April 1, 2013

Ultrafast solvent-assisted electronic level crossing in 1-naphthol

Fabrizio Messina1, Mirabelle Prémont-Schwarz, Olivier Braem

  • 1SB/ISIC/LSU, Ecole Polytechnique Fédérale de Lausanne, Station 6, EPFL, 1015 Lausanne-Dorigny, Switzerland.

Angewandte Chemie (International Ed. in English)
|June 25, 2013
PubMed
Summary

No abstract available in PubMed .

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Fast reactions occurring in times shorter than the time needed to mix reactants pose a unique challenge for investigation. In a liquid-phase continuous-flow system, reactants A and B are swiftly pushed into the mixing chamber, where mixing occurs within 1 ms. The reaction mixture then flows through an observation tube, and one measures light absorption to determine species concentrations at various points of the tube. This method is most appropriate when relatively large volumes of reactants...

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