Related Experiment Video
Updated: May 10, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
Aqua-trimeth-yl[2-(4-methyl-pyrimidin-2-ylsulfan-yl)acetato-κO]tin(IV)
Zhiqing Gao1, Junhong Zhang, Xuyi Hao
1Dongcheng College of Liaocheng University, Shandong 252059, People's Republic of China.
Abstract:
In the title compound, [Sn(CH3)3(C7H7N2O2S)(H2O)], the Sn(IV) atom has a distorted trigonal-bipyramidal coordination geometry, with one carboxyl-ate O atom of the 2-(4-methyl-pyrimidine-2-sulfan-yl)acetate ligand and the O atom of a water mol-ecule in axial positions, and three methyl groups in equatorial positions. In the crystal, mol-ecules are linked via O-H⋯O and O-H⋯N hydrogen bonds, forming double-stranded chains propagating along [010].
Related Concept Videos
Radical Substitution: Hydrogenolysis of Alkyl Halides with Tributyltin Hydride
The bonds formed in this reaction are stronger than the bonds broken, making it energetically favorable. The reaction follows a radical chain mechanism similar to radical halogenation reactions,...
EDTA: Chemistry and Properties
EDTA: Auxiliary Complexing Reagents
