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Updated: May 10, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
1-(4-Chloro-phen-yl)-2-(1,3-diazepan-2-yl-idene)ethanone
Xiao-Wei Zhang1, Jian-Hui Xia, Zhao-Hui Xu
1College of Chemistry and Chemical Engineering, Jiang Xi Normal University, Nanchang, Jiang Xi 330022, People's Republic of China.
Abstract:
In the title compound, C13H15ClN2O, there are two crystallographically independent but conformationally similar (E)-mol-ecules in the asymmetric unit [dihedral angles between the phenyl ring and a common planar fragment of the 1,3-diazepane moiety = 47.34 (16) and 48.00 (16)°]. The seven-membered ring system adopts a chair conformation in both molecules. In the crystal, N-H⋯O hydrogen bonds lead to chains extending along the b-axis direction.
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