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Template-free synthesis of uniform single-crystal hollow cerium dioxide nanocubes and their catalytic activity
Xiguang Han1, Liang Li, Chao Wang
1Department of Chemistry, School of Chemistry and Chemical Engineering, Jiangsu Normal University, Xuzhou, 221116, PR China. xghan@jsnu.edu.cn
Abstract:
Monodisperse single-crystal hollow cerium dioxide nanocubes with exposed (001) facets have been synthesized with the assistance of ammonium chloride (NH4Cl) and polyvinylpyrrolidone (PVP) in a water and ethanol system. A series of experiments indicate that ammonium ion plays an important role in the formation of the hollow structure and PVP plays a key role in the formation of a cubic shape. The hollow cerium dioxide nanocubes exhibit excellent CO catalytic oxidation activity.
