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Updated: May 9, 2026

Infrared Degenerate Four-wave Mixing with Upconversion Detection for Quantitative Gas Sensing
Published on: March 22, 2019
Highly sensitive and fast detection of propane-butane using a 3 μm quantum cascade laser
Jana Jágerská1, Béla Tuzson, Herbert Looser
1Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Air Pollution and Environmental Technology, Überlandstrasse 129, Dübendorf 8600, Switzerland. jana.jagerska@empa.ch
Abstract:
A mid-IR optical analyzer based on a 3 μm Fabry-Perot quantum cascade laser has been developed for ultrafast detection of aerosol propellants, such as propane and butane. Given the laser emission bandwidth of 35 cm(-1), the system is spectrally well-matched to the C-H vibrational band of hydrocarbons, it is insusceptible to water interference, and stable enough to operate without wavelength scanning. Thus, it offers both high sensitivity and speed, reaching 1 ppm precision within a measurement time of 10 ms. The performance of the instrument is evaluated with an industrial demonstrator for aerosol cans leak testing, confirming that, in compliance with international directives, it can detect leaks of 1.2×10(-4) slpm at a rate of 500 cans per minute.
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