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Related Experiment Video

Updated: May 9, 2026

Layer-by-layer Synthesis and Transfer of Freestanding Conjugated Microporous Polymer Nanomembranes
09:09

Layer-by-layer Synthesis and Transfer of Freestanding Conjugated Microporous Polymer Nanomembranes

Published on: December 15, 2015

Conjugated microporous polymers: design, synthesis and application.

Yanhong Xu1, Shangbin Jin, Hong Xu

  • 1Department of Materials Molecular Science, Institute for Molecular Science, National Institutes of Natural Sciences, 5-1 Higashiyama, Okazaki 444-8787, Japan. jiang@ims.ac.jp.

Chemical Society Reviews
|July 13, 2013
PubMed
Summary

Conjugated microporous polymers (CMPs) are novel organic materials with both π-conjugated systems and nanopores. Their unique structure enables diverse applications in energy and environmental solutions.

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Nanotechnology

Background:

  • Conjugated microporous polymers (CMPs) are a unique class of organic porous polymers.
  • They uniquely combine π-conjugated skeletons with permanent nanopores, distinguishing them from non-conjugated porous materials and nonporous conjugated polymers.

Purpose of the Study:

  • To review the molecular design principles, synthetic advancements, and functional applications of CMPs.
  • To highlight the potential of CMPs in addressing energy and environmental challenges.

Main Methods:

  • Review of literature on CMP synthesis and characterization.
  • Analysis of structure-property relationships in CMPs.
  • Exploration of CMP applications in energy and environmental fields.

Main Results:

  • CMPs offer high flexibility in molecular design for both conjugated skeletons and nanopores.
  • A wide variety of CMPs with diverse structures and properties have been synthesized.
  • CMPs demonstrate excellent performance in gas adsorption, catalysis, light emission, harvesting, and energy storage.

Conclusions:

  • CMPs represent a versatile platform for developing advanced functional materials.
  • Their unique properties position them as promising candidates for tackling critical energy and environmental issues.
  • Further research into CMPs will drive innovation in materials science and sustainable technologies.