Precursor driven one pot synthesis of wurtzite and chalcopyrite CuFeS2
Prashant Kumar1, Sitharaman Uma, Rajamani Nagarajan
1Materials Chemistry Group, Department of Chemistry, University of Delhi, Delhi 110007, India.
Abstract:
A facile precursor dependent single step, one pot solution based synthesis of wurtzite and chalcopyrite polymorphs of CuFeS2 has been developed by reacting a Cu(I) thiourea complex with Fe2(SO4)3 and FeCl3 separately in ethylene glycol. The phases have been characterized by structural refinements, SEM-EDX, TEM-SAED, Raman, UV-Visible spectroscopy and TGA measurements.
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