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Published on: October 29, 2013
PHIP-label: parahydrogen-induced polarization in propargylglycine-containing synthetic oligopeptides
Marco Körner1, Grit Sauer, Andreas Heil
1TU Darmstadt, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Petersenstr. 20, Darmstadt, Germany.
Chemical Communications (Cambridge, England)
|July 27, 2013
Abstract:
The unsaturated side chain of l-propargylglycine (Pra) was used to study parahydrogen-induced polarization (PHIP) in synthetic oligopeptides. For the first time PHIP-induced NMR signal enhancement was demonstrated using model peptides bearing various functional side chains.
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