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Measurement of cloud point temperature in polymer solutions
G A Mannella1, V La Carrubba, V Brucato
1Department of Civil, Environmental, Aerospace and Materials Engineering (DICAM), University of Palermo, Viale delle Scienze Ed. 8, 90128 Palermo, Italy. gianluca.mannella@unipa.it
Abstract:
A temperature-controlled turbidity measurement apparatus for the characterization of polymer solutions has been instrumented and set up. The main features are the coupled temperature-light transmittance measurement and the accurate temperature control, achieved by means of peltier cells. The apparatus allows to measure cloud point temperatures by adopting different cooling protocols: low rate for quasi-equilibrium measurements and high rate for detect kinetic effects. A ternary polymeric solution was adopted as case study system showing that cooling rate affects the measured cloud point temperature.
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