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Updated: May 9, 2026

Synthetic Methodology for Asymmetric Ferrocene Derived Bio-conjugate Systems via Solid Phase Resin-based Methodology
Published on: March 12, 2015
Donor-acceptor meso-alkynylated ferrocenyl BODIPYs: synthesis, structure, and properties
Rajneesh Misra1, Bhausaheb Dhokale, Thaksen Jadhav
1Department of Chemistry, Indian Institute of Technology Indore, Indore 452 017, India. rajneeshmisra@iiti.ac.in
Abstract:
meso-Alkynylated ferrocenyl BODIPYs (3-6) with varying conjugation length have been designed, and synthesized using the palladium catalyzed Sonogashira cross-coupling reaction of meso-chloro BODIPY with the corresponding ferrocenylethynes. These BODIPYs have been designed to improve the electronic communication between the donor ferrocene, and the acceptor BODIPY. The photonic and electrochemical properties indicate charge transfer (CT) from the ferrocene to the BODIPY. Single crystal X-ray structures of 2', 3, and 6 show interesting supramolecular interactions. Computational studies were used to study the electronic structure of the BODIPYs.
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