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Updated: May 9, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
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The 2-phosphaethynolate anion: a convenient synthesis and [2+2] cycloaddition chemistry

Andrew R Jupp1, Jose M Goicoechea

  • 1Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA (UK) http://research.chem.ox.ac.uk/jose-goicoechea.aspx.

Angewandte Chemie (International Ed. in English)
|August 6, 2013
PubMed
Summary

Researchers synthesized a novel phosphaethynolate anion from the heptaphosphide trianion. This anion then reacted with diphenylketene and a carbodiimide to form unique four-membered phosphorus-containing rings.

Keywords:
cycloadditionorganophosphorus chemistryphosphaethynolate anionphosphoruspolyphosphides

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