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Related Concept Videos

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
Network Covalent Solids02:18

Network Covalent Solids

Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
Formation of Complex Ions03:45

Formation of Complex Ions

A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
Ionic Crystal Structures02:42

Ionic Crystal Structures

Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...

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Updated: May 9, 2026

Flow-assisted Dielectrophoresis: A Low Cost Method for the Fabrication of High Performance Solution-processable Nanowire Devices
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Flow-assisted Dielectrophoresis: A Low Cost Method for the Fabrication of High Performance Solution-processable Nanowire Devices

Published on: December 7, 2017

Solution-solid-solid mechanism: superionic conductors catalyze nanowire growth.

Junli Wang1, Kangmin Chen, Ming Gong

  • 1Scientific Research Academy and School of Materials Science & Engineering, Jiangsu University , Zhenjiang 212013, Jiangsu, P. R. China.

Nano Letters
|August 8, 2013
PubMed
Summary
This summary is machine-generated.

A novel solution-solid-solid (SSS) mechanism enables efficient synthesis of semiconductor nanowires using superionic conductor nanocrystals. This method facilitates the growth of various II-VI semiconductor nanowires at low temperatures.

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Published on: June 18, 2013

Area of Science:

  • Materials Science
  • Nanotechnology
  • Solid-State Chemistry

Background:

  • Catalytic mechanisms are crucial for producing crystalline semiconductor nanowires.
  • The selection, state, and structure of catalysts are key research areas in nanowire synthesis.

Purpose of the Study:

  • To introduce and elucidate a novel solution-solid-solid (SSS) mechanism for nanowire growth.
  • To demonstrate the catalytic role of solid-phase superionic conductor nanocrystals in low-temperature solution synthesis.

Main Methods:

  • Utilized a solution-solid-solid (SSS) approach for nanowire fabrication.
  • Employed silver selenide (Ag2Se) nanocrystals as catalysts for zinc selenide (ZnSe) nanowire growth.
  • Investigated the growth of other II-VI semiconductor nanowires (CdSe, ZnS, CdS) using various superionic chalcogenides (Ag2S, Cu2S).

Main Results:

  • Successfully demonstrated the SSS mechanism for growing ZnSe nanowires at 100-210 °C.
  • Showcased the extendibility of the SSS model to synthesize other II-VI semiconductor nanowires.
  • Attributed the catalytic efficiency to the unique structural characteristics of superionic conductors, including high vacancy density and cation mobility.

Conclusions:

  • The SSS mechanism provides an efficient route for synthesizing diverse semiconductor nanowires.
  • Superionic conductor nanocrystals exhibit exceptional catalytic properties due to their intrinsic structural features.
  • The study offers insights into solid solution formation and solid-state ion transport at the catalyst-nanowire interface.