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Shaping crystals with light: crystal-to-crystal isomerization and photomechanical effect in fluorinated azobenzenes

Oleksandr S Bushuyev1, Anna Tomberg, Tomislav Friščić

  • 1Department of Chemistry and FRQNT Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, H3A 0B8, Montreal, Canada.

Journal of the American Chemical Society
|August 9, 2013
PubMed

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In the late 1800s, the revelation that light extended beyond visible wavelengths led to the discovery of X-rays by Wilhelm Roentgen. Recognized as high-energy electromagnetic radiation with short wavelengths, X-rays prompted exploration into their interaction with crystals. Max von Laue proposed in 1912 that the periodic arrangement of atoms, ions, or molecules in crystals would cause them to diffract X-rays, a hypothesis confirmed through experiments with copper sulfate and zinc sulfide...