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Updated: May 8, 2026
Electrospinning of Photocatalytic Electrodes for Dye-sensitized Solar Cells
Published on: June 28, 2017
Nanosilver-decorated TiO2 nanofibers coated with a SiO2 layer for enhanced light scattering and localized surface
Sun Hye Hwang1, Jongmin Roh, Jyongsik Jang
1World Class University (WCU) program of Chemical, Convergence for Energy & Environment (C2E2), School of Chemical and Biological Engineering, College of Engineering, Seoul National University, Daehak-dong, Seoul 151-747 (Korea), Fax: (+82) 2-888-7295.
Abstract:
Enhanced harvesting of visible light is vital to the development of highly efficient dye-sensitized solar cells (DSSCs). Nanosilver-decorated TiO2 nanofibers (Ag@TiO2 NFs) were synthesized by depositing chemically reduced Ag ions onto the surface of electrospun TiO2 nanofibers (TiO2 NFs). The prepared Ag@TiO2 NFs were coated with SiO2 (SiO2@Ag@TiO2 NFs) by using PVP as coupling agent for protecting corrosion of Ag nanoparticle by I(-)/I3(-) solution. The fabricated SiO2@Ag@TiO2 NFs demonstrated a synergistic effect of light scattering and surface plasmons, leading to an enhanced light absorption. Moreover, an anode consisting of SiO2@Ag@TiO2 NFs incorporating TiO2 nanoparticles (NPs) increased light harvesting without substantially sacrificing dye attachment. The power conversion efficiency increased from 6.8 to 8.7 % for a thick film (10 μm), that is, 28 %. These results suggest that SiO2@Ag@TiO2 NFs are promising materials for enhanced light absorption in dye-sensitized solar cells.
