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Resonance Fluorescence of an InGaAs Quantum Dot in a Planar Cavity Using Orthogonal Excitation and Detection
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Linear cavity optical-feedback cavity-enhanced absorption spectroscopy with a quantum cascade laser.

A G V Bergin1, G Hancock, G A D Ritchie

  • 1Department of Chemistry, The Physical and Theoretical Chemistry Laboratory, The University of Oxford, Oxford, UK.

Optics Letters
|August 14, 2013
PubMed
Summary

A new optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) method using a quantum cascade laser achieves high sensitivity for NO detection. This technique demonstrates a noise-equivalent absorption coefficient of 2.4×10(-8) cm(-1).

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Area of Science:

  • Spectroscopy
  • Laser Technology
  • Chemical Sensing

Background:

  • Cavity-enhanced absorption spectroscopy (CEAS) offers high sensitivity for trace gas detection.
  • Quantum cascade lasers (QCLs) provide compact and tunable mid-infrared sources.
  • Optical feedback can enhance the performance of laser-based spectroscopic techniques.

Purpose of the Study:

  • To demonstrate optical-feedback cavity-enhanced absorption spectroscopy (OF-CEAS) at 5.5 μm.
  • To achieve high sensitivity and temporal stability for gas detection.
  • To evaluate the performance for nitrogen monoxide (NO) detection.

Main Methods:

  • Utilized a continuous-wave distributed feedback quantum cascade laser (cw DFB-QCL).
  • Coupled the DFB-QCL to a two-mirror linear optical cavity.
  • Implemented OF-CEAS to measure absorption spectra.

Main Results:

  • Successfully demonstrated OF-CEAS at 5.5 μm.
  • Achieved a noise-equivalent absorption coefficient, α(min), of 2.4×10(-8) cm(-1) with 1-second averaging.
  • Identified etalon-fringing as the limiting factor for sensitivity.
  • Demonstrated NO detection down to 5 parts per billion (ppb) within 2 seconds due to temporal stability.

Conclusions:

  • OF-CEAS using a cw DFB-QCL is a viable technique for sensitive gas detection at 5.5 μm.
  • The system exhibits excellent temporal stability, enabling rapid and low-level detection of gases like NO.
  • Further improvements may involve mitigating etalon-fringing effects to enhance sensitivity.