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Fabricating Reactive Surfaces with Brush-like and Crosslinked Films of Azlactone-Functionalized Block Co-Polymers
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Surface patterning using two-phase laminar flow and in situ formation of aryldiazonium salts

Andrew J Gross1, Volker Nock, Matthew I J Polson

  • 1MacDiarmid Institute for Advanced Materials and Nanotechnology, Department of Chemistry, University of Canterbury, Christchurch 8140 (New Zealand).

Angewandte Chemie (International Ed. in English)
|August 14, 2013
PubMed
Abstract

No abstract available in PubMed .

Keywords:
aryltriazenediazo compoundsmicrofluidic channelsradical reactionssurface chemistry

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Nucleophilic Aromatic Substitution of Aryldiazonium Salts: Aromatic SN101:14

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Treating arylamines with nitrous acid gives aryldiazonium salts that are effective substrates in nucleophilic aromatic substitution reactions. The diazonio group in these salts can be easily displaced by different nucleophiles, yielding a wide variety of substituted benzenes. The leaving group departs as nitrogen gas, and this easy elimination is the driving force for the substitution reaction.
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