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Updated: May 8, 2026

A Microwave-Assisted Direct Heteroarylation of Ketones Using Transition Metal Catalysis
Published on: February 16, 2020
Microwave spectrum and molecular structure of vinyl chloride-acetylene, a side binding complex
Helen O Leung1, Mark D Marshall, Fan Feng
1Department of Chemistry, Amherst College , P.O. Box 5000, Amherst, Massachusetts 01002-5000, United States.
Abstract:
The structure of the gas-phase bimolecular complex formed between vinyl chloride and acetylene is determined using a combination of broad-band, chirped-pulse, and narrow-band, Balle-Flygare Fourier transform microwave spectroscopy from 5.8 to 20.7 GHz. Although all previous examples of complexes formed between protic acids and haloethylenes are observed to have similar modes of binding regardless of the specific identity of the acid, HF, HCl, or HCCH, the vinyl chloride-HCCH complex has HCCH located at one end of the vinyl chloride with the secondary interaction occurring with the geminal hydrogen atom as opposed to the "top" binding configuration found for vinyl chloride-HF. Nevertheless, the details of the structure, such as hydrogen bond length (3.01 Å) and amount of deviation from linearity (58.5°), do reflect the strength of the interaction and show clear correlations with the gas-phase acidity. Comparison with analogous complexes allows the determination of the relative importance of electrostatic interactions and steric requirements in leading to the observed structures.
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