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Hongqi Sun1, Yuxian Wang, Shizhen Liu

  • 1Department of Chemical Engineering, Curtin University, GPO Box U1987, Perth, Western Australia 6845, Australia. Shaobin.wang@curtin.edu.au h.sun@curtin.edu.au.

Chemical Communications (Cambridge, England)
|August 16, 2013
PubMed

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Oximes can be reduced to primary amines using catalytic hydrogenation, hydride reduction, or sodium metal reduction. The reduction of aliphatic and aromatic nitro compounds to primary amines takes place by either catalytic hydrogenation or by using active metals like Fe, Zn, and Sn in the presence of an acid.
Though catalytic hydrogenation can reduce nitrobenzenes, the reduction is nonselective in the presence of other functional groups. For instance, if nitrobenzene contains an aldehyde group,...