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The Diffusion of Passive Tracers in Laminar Shear Flow
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Effective diffusivity in transient state.

Zbisław Tabor1, Paweł Nowak, Małgorzata Krzak

  • 1Cracow University of Technology, Warszawska 24, 31-155 Krakow, Poland. tabor.zbislaw@gmail.com

The Journal of Chemical Physics
|August 24, 2013
PubMed
Summary
This summary is machine-generated.

This study investigates diffusion in finite composite media under transient conditions. Numerical modeling reveals that the effective diffusion coefficient can differ from predictions of the Kalnin-Kotomin model for stationary diffusion.

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Area of Science:

  • Materials Science
  • Chemical Engineering
  • Physical Chemistry

Background:

  • The Kalnin-Kotomin model, an extension of the Maxwell-Garnett formula, is commonly used to predict effective diffusivity in polymer composites.
  • This model accurately describes stationary diffusion in infinite media but has limitations for transient diffusion in finite systems.

Purpose of the Study:

  • To investigate diffusion in finite composite media under transient conditions.
  • To numerically model the diffusion process and estimate the effective diffusion coefficient in the transient state.
  • To develop an analytical model explaining deviations from the stationary diffusion predictions.

Main Methods:

  • Numerical modeling of diffusion processes in composite media.
  • Estimation of the effective diffusion coefficient under transient conditions.
  • Development of an analytical model to account for transient effects.

Main Results:

  • The effective diffusion coefficient in finite systems under transient conditions can differ from predictions based on the Kalnin-Kotomin model.
  • Numerical simulations provide estimates for the transient effective diffusion coefficient.
  • An analytical model is proposed to explain these transient deviations.

Conclusions:

  • The Kalnin-Kotomin model's predictions for effective diffusivity may not hold for finite systems under transient diffusion.
  • Transient diffusion in composite materials requires specialized modeling beyond stationary state assumptions.
  • The proposed analytical model offers insights into the behavior of diffusion in finite, transient composite systems.