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One-procedure synthesis of capsiate from capsaicin by lipase-catalyzed dynamic transacylation

Kohji Ishihara1, Soon-Il Kwon, Noriyoshi Masuoka

  • 1Graduate School of Science, Okayama University of Science, 1-1 Ridai-cho, Kita-ku, Okayama, 700-0005, Japan, ishihara@dls.ous.ac.jp.

World Journal of Microbiology & Biotechnology
|September 13, 2013
PubMed

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Esters can be hydrolyzed to carboxylic acids under acidic or basic conditions. Base-promoted hydrolysis of esters is a nucleophilic acyl substitution reaction in which esters react with an aqueous base, followed by an acid to give carboxylic acids. This reaction is also known as saponification because it forms the basis for making soaps from fats.
The reaction requires a base in stoichiometric amounts, which participates in the reaction and is not regenerated later. So, the base acts as a...