Lehmann effects and rotatoelectricity in liquid crystalline systems made of achiral molecules

We discuss Lehmann effects and rotato-electricity for liquid crystalline phases made of achiral molecules. We point out that for static and dynamic Lehmann effects to exist, it is not necessary to have chiral molecules provided the overall structure has macroscopic chirality. This question is of direct relevance for liquid crystalline phases formed by bent-core molecules provided they have a sufficiently low symmetry. This includes systems which break parity symmetry and have overall C(2) or C(1) symmetry. We point out that for liquid crystalline gels and elastomers one should be able to observe rotato-electricity for systems with macroscopic chirality. Rotatoelectricity is associated with the relative rotations between two subsystems, namely, between the network and the director, in an external electric field. Candidates include gels and even monolayers prepared from bent-core molecules with sufficiently low symmetry.