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A manganese-doped polymeric framework of polyoxotitanate nanoclusters with a narrow band gap
Yang Chen1, Jesse D Sokolow, Elzbieta Trzop
1Chemistry Department, University at Buffalo, SUNY, Buffalo, New York 14260-3000, USA. coppens@buffalo.edu ychen37@buffalo.edu.
Dalton Transactions (Cambridge, England : 2003)
|September 18, 2013
Abstract:
A three-dimensional coordination polymer based on a manganese-doped polyoxotitanate nanocluster, {Ti13Mn4O16[MeC(CH2O)3]4(OEt)12Br4}∞, has been synthesized under solvothermal conditions. It is the first framework of doped polyoxotitanate nanoclusters reported in the literature. Compared with anatase, its band gap is reduced from 3.19 to 2.57 eV.
