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Updated: May 7, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
Three-dimensional {Co(3+)-Zn2+} and {Co(3+)-Cd2+} networks originated from carboxylate-rich building blocks:
1Department of Chemistry, University of Delhi , Delhi 110 007, India.
Abstract:
The present work shows the utilization of Co(3+) complexes appended with either para- or meta-arylcarboxylic acid groups as the molecular building blocks for the construction of three-dimensional {Co(3+)-Zn(2+)} and {Co(3+)-Cd(2+)} heterobimetallic networks. The structural characterizations of these networks show several interesting features including well-defined pores and channels. These networks function as heterogeneous and reusable catalysts for the regio- and stereoselective ring-opening reactions of various epoxides and size-selective cyanation reactions of assorted aldehydes.
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