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Related Concept Videos

Metal-Ligand Bonds02:51

Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Metallic Solids02:37

Metallic Solids

Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability. Many...
Valence Bond Theory02:42

Valence Bond Theory

Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...

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Updated: May 7, 2026

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

Published on: June 14, 2024

Patchy particle self-assembly via metal coordination.

Yufeng Wang1, Andrew D Hollingsworth, Si Kyung Yang

  • 1Molecular Design Institute and Department of Chemistry, New York University , New York, New York 10003, United States.

Journal of the American Chemical Society
|September 19, 2013
PubMed
Summary
This summary is machine-generated.

Researchers used metal coordination to control the self-assembly of patchy colloids into chain structures. This novel approach allows for precise control over colloidal assembly for advanced materials design.

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Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
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Origami Inspired Self-assembly of Patterned and Reconfigurable Particles
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Origami Inspired Self-assembly of Patterned and Reconfigurable Particles

Published on: February 4, 2013

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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
06:48

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles

Published on: June 14, 2024

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
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Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

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Origami Inspired Self-assembly of Patterned and Reconfigurable Particles
12:33

Origami Inspired Self-assembly of Patterned and Reconfigurable Particles

Published on: February 4, 2013

Area of Science:

  • Materials Science
  • Supramolecular Chemistry
  • Colloid Science

Background:

  • Colloidal self-assembly is crucial for creating complex materials.
  • Controlling interactions between colloidal particles is key to directing assembly.
  • Metal coordination offers specific binding interactions for molecular recognition.

Purpose of the Study:

  • To demonstrate the use of metal coordination as a specific force in colloidal self-assembly.
  • To fabricate poly(styrene)-based patchy particles with high-symmetry patches.
  • To assemble these particles into larger chain architectures.

Main Methods:

  • Fabrication of cross-linked poly(styrene)-based patchy particles via a two-stage swelling and polymerization method.
  • Site-specific functionalization of particle patches with carboxylic acid groups.
  • Attachment of either a triblock copolymer (TBC) with palladated pincer receptors or a small molecule with a pyridine headgroup.

Main Results:

  • Successful assembly of functionalized patchy colloids into chain architectures.
  • Demonstration of metal coordination as a specific driving force for self-assembly.
  • TBC functionalization allows independent tuning of interaction range and recognition motif.

Conclusions:

  • Metal coordination is a viable and specific strategy for directing colloidal self-assembly.
  • The developed methodology enables the creation of complex colloidal chain architectures.
  • This approach offers design flexibility for advanced functional materials.