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Why compete when you can share? Competitive reactivity of germanium and phosphorus with selenium
Eric C Y Tam1, Lisa M Harris, Elliot S Borren
1Department of Chemistry, University of Sussex, Falmer, Brighton, BN1 9QJ, UK.
Abstract:
Addition of one equivalent of selenium to a germanium-phosphanide complex results in insertion of selenium into the Ge-P bond, not oxidation at germanium or phosphorus. Addition of excess selenium results in oxidation at phosphorus, although of germanium oxidation is still observed.
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