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Published on: August 16, 2018
5,6-Dimeth-yl-1,10-phenanthroline
1Chemistry Department and Chemical Sciences Division of Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720, USA.
Abstract:
In the title compound, C14H12N2, the N⋯N distance is 2.719 (1) Å. The N-C-C-N torsion angle [0.9 (1)°] is close to the ideal value of 0° as expected. Bond lengths and angles are consistent with those observed for [1,10]phenanthroline and coordinated 5,6 dimeth-yl[1,10]phenanthroline. In the crystal, C-H⋯N hydrogen bonds link the mol-ecules into C(4) chains running parallel to the b axis. Weak π-π inter-actions between benzene and pyridine rings [centroid-centroid distance = 3.5337 (7) Å] and between benzene rings [centroid-centroid distances = 3.6627 (7) and 3.8391 (7)Å] also occur.
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