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Updated: May 7, 2026

Strain Sensing Based on Multiscale Composite Materials Reinforced with Graphene Nanoplatelets
Published on: November 7, 2016
Functionalized low defect graphene nanoribbons and polyurethane composite film for improved gas barrier and
Changsheng Xiang1, Paris J Cox, Akos Kukovecz
1Department of Chemistry, ‡Department of Mechanical Engineering and Materials Science, and the §Smalley Institute for Nanoscale Science and Technology, Rice University , 6100 Main Street, Houston, Texas 77005, United States.
Abstract:
A thermoplastic polyurethane (TPU) composite film containing hexadecyl-functionalized low-defect graphene nanoribbons (HD-GNRs) was produced by solution casting. The HD-GNRs were well distributed within the polyurethane matrix, leading to phase separation of the TPU. Nitrogen gas effective diffusivity of TPU was decreased by 3 orders of magnitude with only 0.5 wt % HD-GNRs. The incorporation of HD-GNRs also improved the mechanical properties of the composite films, as predicted by the phase separation and indicated by tensile tests and dynamic mechanical analyses. The improved properties of the composite film could lead to potential applications in food packaging and lightweight mobile gas storage containers.

