Synthesis, characterization and reactivity of potassium and barium complexes containing phosphane-borane stabilized...

The polymeric potassium complex [K{CH(PPh2BH3)2}]∞ (1) was prepared and used as a starting material for the syntheses of related N,N,N',N'-tetramethylethylenediamine (tmeda) and N,N,N',N',N''-pentamethyldiethylenetriamine (pmdta) ligated potassium derivatives [K{CH(PPh2BH3)2}(tmeda)2]∞ (2) and [K{CH(PPh2BH3)2}(pmdta)]2 (3). Salt metathesis reactions with [BaI2(thf)5] allowed the synthesis of the barium derivatives [BaI{CH(PPh2BH3)2}(thf)5] (5) and [Ba{CH(PPh2BH3)2}2(solv)2}] (solv = Et2O, thf) (6), which are more prone to subsequent reactions than the potassium derivatives. One of the resulting products, [Ba4O{CH(PPh2BH3)2}3{Ph2PCH(BH3)PPh2BH3}3] (7), which contains two different isomeric forms of the bis(borane) adduct of Ph2PCHPPh2, was isolated. The complexes were characterized by NMR techniques and single crystal X-ray diffraction measurements.