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4-Nitro-3-(5-tetrazole)furoxan and its salts: synthesis, characterization, and energetic properties

Lixuan Liang1, Kai Wang, Chengming Bian

  • 1School of Chemical Engineering and the Environment, Beijing Institute of Technology, Beijing, 100081 (P. R. China), Fax: (+86) 10-68918982.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|October 10, 2013
PubMed

Keywords:
X-ray diffractiondetonation performanceenergetic materialsfuroxannitrogen heterocycles

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.