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Updated: May 7, 2026
Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
Rational design of porous coordination polymers based on bis(phosphine)MCl2 complexes that exhibit high-temperature
Alisha M Bohnsack1, Ilich A Ibarra, Vladimir I Bakhmutov
1Department of Chemistry, The University of Texas at Austin , Austin, Texas 78712-1224, United States.
Abstract:
MCl2 complexes of a new p-carboxylated 1,2-bis(diphenylphosphino)benzene ligand are effectively utilized as tetratopic building blocks to prepare isostructural porous coordination polymers with accessible reactive metal sites (M = Pd, Pt). The crystalline materials exhibit unusual and fully reversible H2 sorption at 150 °C. Post-synthetic reactivity is also possible, in which Pt-Cl bonds can be activated to provide organometallic species in the pores.
