Influence of long-range interactions on charge ordering phenomena on a square lattice
Louk Rademaker1, Yohanes Pramudya, Jan Zaanen
1Institute-Lorentz for Theoretical Physics, Leiden University, PO Box 9506, NL-2300 RA Leiden, The Netherlands.
Abstract:
Usually complex charge ordering phenomena arise due to competing interactions. We have studied how such ordered patterns emerge from the frustration of a long-ranged interaction on a lattice. Using the lattice gas model on a square lattice with fixed particle density, we have identified several interesting phases, such as a generalization of Wigner crystals at low particle densities and stripe phases at densities between ρ=1/3 and 1/2. These stripes act as domain walls in the checkerboard phase present at half-filling. The phases are characterized at zero temperatures using numerical simulations, and mean field theory is used to construct a finite temperature phase diagram.
More Related Videos
Related Concept Videos
Trends in Lattice Energy: Ion Size and Charge
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than...
Lattice Energies of Ionic Crystals
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Valence Bond Theory
Coulomb's Law
Newton's third law applies to the Coulomb force — the...


