Relation between shape of liquid-gas interface and evolution of buoyantly unstable three-dimensional chemical fronts

Buoyantly unstable 3D chemical fronts were seen traveling through an iodate-arsenous acid reaction solution. The experiments were performed in channel reactors with rectangular cross sections, where the top of the reaction solution was in contact with air. A concave or convex meniscus was pinned to reactor lateral walls. Influence of the meniscus shape on front development was investigated. For the concave meniscus, an asymptotic shape of fronts holding negative curvature was observed. On the other hand, fronts propagating in the solution with the convex meniscus kept only positive curvature. Those fronts were also a bit faster than fronts propagating in the solution with the concave meniscus. A relation between the meniscus shape, flow distribution, velocity, and shape is discussed.