Magnetic poles determinations and robustness of memory effect upon solubilization in a Dy(III)-based single ion
Tamyris T da Cunha1, Julie Jung, Marie-Emmanuelle Boulon
1Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1 , 263 Avenue du Général Leclerc, 35042 Rennes Cedex, France.
Abstract:
The [Dy(tta)3(L)] complex behaves as a single ion magnet both in its crystalline phase and in solution. Experimental and theoretical magnetic anisotropy axes perfectly match and lie along the most electro-negative atoms of the coordination sphere. Both VSM and MCD measurements highlight the robustness of the complex, with persistence of the memory effect even in solution up to 4 K.
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