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Updated: May 6, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
[Study on high-temperature phase change of tobermorite]
Xiu-Li Yang1, Xiao-Yu Cui, Chong Cui
1School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China. jkyxl@126.com
High-temperature heating of tobermorite causes dehydration and dehydroxylation, transforming its structure into stable wollastonite at 1000°C. This phase change involves structural collapse and recrystallization.
Area of Science:
- Materials Science
- Mineralogy
- Geochemistry
Context:
- Tobermorite is a calcium silicate hydrate (CSH) mineral crucial in cementitious materials.
- Understanding its thermal stability is vital for high-temperature applications and geological processes.
Purpose:
- To investigate the high-temperature phase transformation of pure tobermorite using thermal analysis and spectroscopy.
- To elucidate the structural changes and intermediate phases during heating.
Summary:
- Heating tobermorite to 300°C resulted in the loss of interlayer water (dehydration).
- Dehydroxylation and structural collapse occurred around 724°C, leading to an amorphous phase.
- Recrystallization to wollastonite began at 861°C, forming a stable 2M-wollastonite structure by 1000°C.
Impact:
- Provides a detailed understanding of tobermorite's thermal decomposition pathway.
- Informs the use of tobermorite-based materials in high-temperature environments.
- Contributes to the knowledge of phase transitions in silicate minerals.
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